LIPIcs.FSTTCS.2008.1750.pdf
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We show that a randomly chosen $3$-CNF formula over $n$ variables with clauses-to-variables ratio at least $4.4898$ is asymptotically almost surely unsatisfiable. The previous best such bound, due to Dubois in 1999, was $4.506$. The first such bound, independently discovered by many groups of researchers since 1983, was $5.19$. Several decreasing values between $5.19$ and $4.506$ were published in the years between. The probabilistic techniques we use for the proof are, we believe, of independent interest.
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