Absorption of Atmospheric CO₂ and Its Transport to the Intermediate Layer in the Okhotsk Sea

Abstract

In the southwestern Okhotsk Sea off Hokkaido we observed chemical components related to the carbonate system for 1 year from August 1997 to June 1998. Using the conservative components salinity and water temperature, we confirmed the existence of two water masses flowing into the intermediate layer of the Okhotsk Sea, the East Sakhalin Current Water (ESCW) which becomes denser by mixing of brine water, and the Forerunner of Soya Warm Current Water (FSWW) which becomes denser due to cooling of the saline Kuroshio water. The ΔNTC_x values were calculated by comparing the ESCW and the FSWW with the Pacific Deep Water (PDW). The ΔNTC_x values obtained are 100–110 μmol/kg and 70–100 μmol/kg for the ESCW and the FSWW off Hokkaido, respectively, which are considerably larger than that of the Kuroshio water. These large ΔNTC_x values may be due to both low DIC concentration in the surface water and intense gas exchange under the cold and stormy winter conditions for the ESCW and the cooling of the FSWW as it flows northward. Since the flow rates of dense waters concerned with the ESCW and the FSWW have previously been estimated as 0.9 Sv and 0.2 Sv, respectively, the amount of atmospheric CO₂ absorbed and transported to the intermediate layer turns out to be 3.9−4.1 × 10¹³ gC/yr. This flux is small on a global scale, but the flux divided by the surface layer of the Okhotsk Sea is 30 gC/m²/yr, which is 5 times greater than the mean absorption flux of anthropogenic CO₂ in the world's oceans. It is thus considered that atmospheric CO₂ is efficiently absorbed in the Okhotsk Sea.