Abstract
Prior to mining, the water in and around the mine is rarely influenced by human activities, and hydrogeochemical processes are the major factors influencing and controlling water chemistry. To identify these natural hydrogeochemical processes in Laoheba phosphorite mine (Sichuan Province, China), correlation and multivariate statistical techniques were used. Results show that water quality in the area is generally good before the Laoheba phosphorite mine goes into construction and production. The cluster analysis classified water samples into 4 clusters (C1–C4). Samples from C1 and C2 are of HCO3−Ca·Mg and HCO3−Ca type, while those from C3 and C4 are of HCO3−Ca·Mg type. Most parameters except Cl− and pH show an increasing trend in the order of C1 to C4. Three principal components were extracted, and PC1 represents the ion exchange and the weathering of calcite, dolomite, and silicate minerals. PC2 and PC3 indicate the process of water recharge from upstream waters and the process of evaporation, respectively. The hydrochemistry of waters in the area is a result of multiple factors, and natural mineral weathering and ion exchange are the most important ones.
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References
Aleksander-Kwaterczak U, Ciszewski D (2012) Groundwater hydrochemistry and soil pollution in a catchment affected by an abandoned lead–zinc mine: functioning of a diffuse pollution source. Environ Earth Sci 65:1179–1189. doi:10.1007/s12665-011-1366-4
Alfy ME (2012) Integrated geostatistics and GIS techniques for assessing groundwater contamination in Al Arish area, Sinai, Egypt. Arab J Geosci 5:197–215. doi:10.1007/s12517-010-0153-y
Arnous MO, El-Rayes AE (2012) An integrated GIS and hydrochemical approach to assess groundwater contamination in West Ismailia area, Egypt. Arab J Geosci. doi:10.1007/s12517-012-0555-0, Online first
Baeza C, Corominas J (2001) Assessment of shallow landslide susceptibility by means of multivariate statistical techniques. Earth Surf Process Landforms 26(12):1251–1263. doi:10.1002/esp.263
Banoeng-Yakubo B, Yidana SM, Nti E (2009) Hydrochemical analysis of groundwater using multivariate statistical methods—the Volta Region, Ghana. KSCE J Civil Eng 13(1):55–63. doi:10.1007/s12205-009-0055-2
Byrne P, Reid I, Wood PJ (2013) Stormflow hydrochemistry of a river draining an abandoned metal mine: the Afon Twymyn, central Wales. Environ Monit Assess 185:2817–2832. doi:10.1007/s10661-012-2751-5
Cloutier V, Lefebvre R, Therrien R, Savard MM (2008) Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system. J Hydrol 353:294–313. doi:10.1016/j.jhydrol.2008.02.015
Dar IA, Sankar K, Shafi ST, Dar MA (2012) Hydrochemistry of groundwater of Thiruporur block, Tamil Nadu (India). Arab J Geosci 5:259–262. doi:10.1007/s12517-010-0203-5
Durov SA (1948) Classification of natural waters and graphic presentation of their composition. Dokl Akad Nauk SSSR 59(1):87–90
Favas PJC, Pratas J, Gomes MEP (2012) Hydrochemistry of superficial waters in the Adoria mine area (Northern Portugal): environmental implications. Environ Earth Sci 65:363–372. doi:10.1007/s12665-011-1097-6
Janson E, Gzyl G, Banks D (2009) The occurrence and quality of mine water in the upper Silesian Coal Basin, Poland. Mine Water Environ 28:232–244. doi:10.1007/s10230-009-0079-3
Koklu R, Sengorur B, Topal B (2010) Water quality assessment using multivariate statistical methods—a case study: Melen River System (Turkey). Water Resour Manage 24:959–978. doi:10.1007/s11269-009-9481-7
Li PY, Qian H, Wu JH (2011) Hydrochemical characteristics and evolution laws of drinking groundwater in Pengyang County, Ningxia, Northwest China. E-J Chem 8(2):565–575. doi:10.1155/2011/472085
Li PY, Qian H, Wu JH, Zhang YQ, Zhang HB (2013a) Major ion chemistry of shallow groundwater in the Dongsheng Coalfield, Ordos Basin, China. Mine Water Environ. doi:10.1007/s10230-013-0234-8, Online first
Li PY, Wu JH, Qian H (2013b) Assessment of groundwater quality for irrigation purposes and identification of hydrogeochemical evolution mechanisms in Pengyang County, China. Environ Earth Sci 69(7):2211–2225. doi:10.1007/s12665-012-2049-5
Makni J, Bouri S, Dhia HB (2013) Hydrochemistry and geothermometry of thermal groundwater of southeastern Tunisia (Gabes region). Arab J Geosci 6:2673–2683. doi:10.1007/s12517-011-0510-5
Ministry of Health of the People’s Republic of China (2006) National Standard of the People’s Republic of China: standard for drinking water quality, GB 5749-2006
Nikolaidis C, Zafiriadis I, Mathioudakis V, Constantinidis T (2010) Heavy metal pollution associated with an abandoned lead–zinc mine in the Kirki Region, NE Greece. Bull Environ Contam Toxicol 85(3):307–312. doi:10.1007/s00128-010-0079-9
Prasad B, Bose J (2001) Evaluation of the heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environ Geol 41(1–2):183–188. doi:10.1007/s002540100380
Qian H, Ma ZY, Li PY (2012) Hydrogeochemistry, 2nd edn. Geologic Publishing House, Beijing (in Chinese)
Razo I, Carrizales L, Castro J, Díaz-Barriga F, Monroy M (2004) Arsenic and heavy metal pollution of soil, water and sediments in a semiarid climate mining area in Mexico. Water Air Soil Pollut 152(1–4):129–152. doi:10.1023/B:WATE.0000015350.14520.c1
Rozkowski A, Chmura A, Gajowiec B, Wagner J (1993) Impact of mining on the groundwater chemistry in the upper Silesian coal basin (Poland). Mine Water Environ 112:95–106. doi:10.1007/BF02914802
Singh AK, Mahato MK, Neogi B, Mondal GC, Singh TB (2011) Hydrogeochemistry, elemental flux, and quality assessment of mine water in the Pootkee-Balihari Mining Area, Jharia Coalfield, India. Mine Water Environ 30(3):197–207. doi:10.1007/s10230-011-0143-7
Tang QY (2010) DPS© data processing system: experimental design, statistical analysis and data mining, 2nd edn. Science Press, Beijing (in Chinese)
Wishart D (1969) An algorithm for hierarchical classifications. Biometrics 25(1):165–170
Xiang G, Zhang HX (2011) Water hydrochemical characteristics and quality assessment based on entropy weighted osculating value method in Laoheba phosphorite mine field in Sichuan, China. South-to-North Water Transfers and Water Science & Technology 9(4):125–129. doi:10.3724/SP.J.1201.2011.04000 (in Chinese)
Yidana SM, Banoeng-Yakubo B, Akabzaa TM (2010) Analysis of groundwater quality using multivariate and spatial analyses in the Ketabasin, Ghana. J Afr Earth Sci 58:220–234. doi:10.1016/j.jafrearsci.2010.03.003
Acknowledgments
The research was supported by the Doctor Postgraduate Technical Project of Chang'an University (2013G5290002 and CHD2011ZY022), the Special Fund for Basic Scientific Research of Central Colleges (CHD2011ZY020 and CHD2012TD003), and the National Natural Science Foundation of China (41172212). We are grateful to the editor and reviewers for their valuable comments. Engineer Xiang G was highly appreciated for providing the basic physiochemical and hydrogeological data of the study.
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Wu, J., Li, P., Qian, H. et al. Using correlation and multivariate statistical analysis to identify hydrogeochemical processes affecting the major ion chemistry of waters: a case study in Laoheba phosphorite mine in Sichuan, China. Arab J Geosci 7, 3973–3982 (2014). https://doi.org/10.1007/s12517-013-1057-4
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DOI: https://doi.org/10.1007/s12517-013-1057-4