A rapid spectral-reflectance-based fingerprinting approach for documenting suspended sediment sources during storm runoff events | Journal of Soils and Sediments
Skip to main content

Advertisement

A rapid spectral-reflectance-based fingerprinting approach for documenting suspended sediment sources during storm runoff events

  • SEDIMENTS, SEC 3 • SEDIMENT MANAGEMENT AT THE RIVER BASIN SCALE • RESEARCH ARTICLE
  • Published:
Journal of Soils and Sediments Aims and scope Submit manuscript

Abstract

Purpose

This paper reports on the development of a rapid and simple spectra-reflectance-based fingerprinting approach for documenting suspended sediment sources during storm runoff events. The methodology was applied in the rural Wollefsbach catchment (4.4 km2, NW Luxembourg).

Materials and methods

Different chemical properties of the sediment retained on glass fibre filters after filtration were predicted from VIS/NIR spectra (ASD FieldSpec-II spectrometer, 0.4–2.5 µm) through partial least-square regression models (PLSR). Chemical property values measured on time-integrated suspended sediment, bed sediment and potential sediment sources samples (topsoil and channel banks) collected in the catchment were used to calibrate the PLSR models. Appropriate properties were selected and used to apply the ‘spectral-reflectance-based fingerprinting approach’, in order to estimate the sources of the suspended sediment retained on the filters. Uncertainty associated with model predictions was assessed using an inclusive approach to mixing models based on Bayesian error estimation, incorporating tracer property variability using a Monte Carlo simulation technique.

Results and discussion

The methodology proved to be a useful, fast and easy to apply approach not only for studying the variation of suspended sediment properties during storm runoff events from spectra, but also for documenting the variation of suspended sediment sources during individual storm events.

Conclusions

The spectral-reflectance-based fingerprinting approach possesses considerable potential, since it possesses a number of important advantages over conventional source fingerprinting techniques, in terms of cost and time and labour requirements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
¥17,985 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Japan)

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Awiti AO, Walsh MG, Shepherd KD, Kinyamario J (2008) Soil condition classification using infrared spectroscopy: a proposition for assessment of soil condition along a tropical forest-cropland chronosequence. Geoderma 143:73–84

    Article  CAS  Google Scholar 

  • Ballentine DJ, Walling DE, Collins AL, Leeks GJ (2008) The phosphorus content of fluvial suspended sediment in three lowland groundater-dominated cacthments. J Hydr 357:140–151

    Article  Google Scholar 

  • Balsam WL, Deaton BC (1996) Determining the composition of the late Quaternary marine sediments from NUV, VIS, and NIR diffuse reflectance spectra. Mar Geol 134:31–55

    Article  CAS  Google Scholar 

  • Ben-Dor E, Banin A (1994) Visible and near-infrared (0.4–1.1 µm) analysis of arid and semiarid soils. Remote Sens Environ 48:261–274

    Article  Google Scholar 

  • Ben-Dor E, Banin A (1995) Near-Infrared analysis as a method to simultaneously evaluate spectral featureless constituents in soil. Soil Sci 159:259–270

    Article  CAS  Google Scholar 

  • Beven K, Binley A (1992) The future of distributed models: calibration and predictive uncertainty. Hydr Process 6:279–298

    Article  Google Scholar 

  • Bilotta GS, Brazier RE (2008) Understanding the influence of suspended solids on water quality and aquatic biota. Water Res 42:2849–2861

    Article  CAS  Google Scholar 

  • Brown D, Shepherd KD, Walsh M, Dewayne Mays M, Reinsch T (2006) Global soil characterization with VNIR diffuse reflectance spectroscopy. Geoderma 132:273–290

    Article  CAS  Google Scholar 

  • Chang CW, Laird DA, Mausbach MJ, Hurburgh CR Jr (2001) Near-infrared reflectance spectroscopy—a principal component regression analysis of soil properties. Soil Sci Soc Am J 65:480–490

    CAS  Google Scholar 

  • Christy CD (2008) Real-time measurement of soil attributes using on-the-go near infrared reflectance spectroscopy. Comput Elect Agric 61:10–19

    Article  Google Scholar 

  • Collins AL, Walling DE (2002) Selecting fingerprint properties for discriminant potential suspended sediment sources in river basins. J Hydr 261:218–244

    Article  CAS  Google Scholar 

  • Collins AL, Walling DE (2004) Documenting catchment suspended sediment sources: problems, approaches and prospects. Prog Phys Geogr 28:159–196

    Article  Google Scholar 

  • Collins AL, Walling DE, Leeks GJ (1997a) Source type ascription for fluvial suspended sediment based on quantitative composite fingerprinting technique. Catena 29:1–27

    Article  CAS  Google Scholar 

  • Collins AL, Walling DE, Leeks GJ (1997b) Use of geochemical record preserved in floodplain deposits to reconstruct changes in river catchment sediment sources. Geomorphol 19:151–167

    Article  Google Scholar 

  • Daniel K, Tripathi N, Honda K (2003) Artificial neural network analysis of laboratory and in situ spectra for the estimation of macronutrients in soils of Lop Buri (Thailand). Aust J Soil Res 41:47–59

    Article  CAS  Google Scholar 

  • Davis MD, Fox JF (2009) Sediment fingerprinting: review of the method and future improvements for allocating nonpoint source pollution. J Environ Eng 135:490–504

    Article  CAS  Google Scholar 

  • Dunn B, Batten G, Ciavarella S (2002) The potential of near-infrared reflectance spectroscopy for soil analysis—a case study from the Riveriene plain of south-eastern Australia. Aust J Exp Agric 42:607–614

    Article  Google Scholar 

  • Efron B, Tibshirani R (1994) An introduction to the bootstrap. Monographs on statistics and applied probability, 57. Chapman and Hall, Boca Raton, p 436

    Google Scholar 

  • Fidêncio P, Poppi R, De Andrade J (2002) Determination of organic matter in soils using radial basis function networks and near infrared spectroscopy. Anal Chem Acta 453:125–134

    Article  Google Scholar 

  • Franks SW, Rowan JS (2000) Multi-parameter fingerprinting of sediment sources: uncertainty estimation and tracer selection. In: Bentley LR, Brebbia CA, Gray WG, Pinder GF, Sykes JF (eds) Computational methods in water resources. Rotterdam, Balkema, pp 1067–1074

    Google Scholar 

  • Horowitz AJ, Stephens VC (2008) The effects of land use on fluvial sediment chemistry for the conterminous U.S.—results from the first cycle of the NAWQA programe: trace and major elements, phosphorous, carbon, and sulfur. Sci Tot Environ 400:290–314

    Article  CAS  Google Scholar 

  • Horowitz AJ, Elrick KA, Smith JJ (2008) Monitoring urban impacts on suspended sediment, trace element, and nutrient fluxes within the City of Atlanta, Georgia, USA: program design, methodological considerations, and initial results. Hydrol Process 22:1473–1496

    Article  CAS  Google Scholar 

  • Hunt GR, Salisbury JW (1970) Visible and near-infrared spectra of minerals and rocks. I Silicate minerals. Mod Geol 1:283–300

    CAS  Google Scholar 

  • Islam K, Singh B, McBratney A (2003) Simultaneous estimation of several soil properties by ultra-violet, visible, and near-infrared reflectance spectroscopy. Aust J Soil Res 41:1101–1114

    Article  CAS  Google Scholar 

  • Kemper T, Sommer S (2002) Estimate of heavy metal contamination in soils after a mining accident using reflectance spectrometry. Environ Sci Technol 36:2742–2747

    Article  CAS  Google Scholar 

  • Kooistra L, Wehners R, Leuven RS, Buydens LM (2001) Possibilities of visible near infrared spectroscopy for the assessment of soil contamination in river floodplains. Anal Chem Acta 446:97–105

    Article  CAS  Google Scholar 

  • Kooistra L, Wanders J, Epema GF, Leuven RE, Wehrens R, Buydens LC (2003) The potential of field spectroscopy for the assessment of sediment properties in river floodplains. Anal Chem Acta 484:189–200

    Article  CAS  Google Scholar 

  • Krause AK, Franks SW, Kalma RJ, Loughran RJ, Rowan JS (2003) Multi-parameter fingerprinting of sediment deposition in a small gullied catchment in SE Australia. Catena 53:327–348

    Article  Google Scholar 

  • Martínez-Carreras N, Gallart F, Iffly JF, Pfister L, Walling DE, Krein A (2008) Uncertainty assessment in suspended sediment fingerprinting based on tracer mixing models: a case study from Luxembourg. Proceedings of a symposium on ‘sediment dynamics in changing environments’. Christchurch, New Zealand. IAHS 325:94–105

    Google Scholar 

  • Martínez-Carreras N, Udelhoven T, Krein A, Gallart F, Iffly JF, Ziebel J, Hoffmann L, Pfister L, Walling DE (2009) The use of sediment colour measured with diffuse reflectance spectrometry to determine sediment sources: application to the Attert River catchment (Luxembourg). J Hydr. doi:10.1016/j.jhydrol.2009.12.017

  • McCarty G, Reeves J III, Reeves V, Follett R, Kimble J (2002) Mid-infrared and near-infrared diffuse reflectance spectroscopy for soil carbon measurements. Soil Soc Am J 66:640–646

    Article  CAS  Google Scholar 

  • Motha J, Wallbrink P, Hairsine P, Grayson R (2003) Determining the sources of suspended sediment in a forested catchment in southeastern Australia. Water Resour Res 39:1056

    Article  Google Scholar 

  • Murphy J, Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters. Anal Chem Acta 27:31–36

    Article  CAS  Google Scholar 

  • Olley J, Caitcheon G (2000) Major element chemistry of sediment from the Darling-Barwon River and its tributaries: implications for sediment and phosphorous sources. Hydr Process 14:1159–1175

    Article  Google Scholar 

  • Owens PN, Walling DE, Leeks GJL (2000) Tracing fluvial suspended sediment sources in the catchment of the River Tweed, Scotland, using composite fingerprints and a numerical mixing model. In: Foster ID (ed) Tracers in geomorphology. Wiley, Chichester, pp 291–307

    Google Scholar 

  • Owens PN, Batalla RJ, Collins AJ, Gomez B, Hicks DM, Horowitz AJ, Kondolf GM, Marden M, Page MJ, Peacock DH, Petticrew EL, Salomons W, Trustrum NA (2005) Fine-grained sediment in river systems: environmental significance and management issues. River Res Applic 21:693–717

    Article  Google Scholar 

  • Pfister L, Humbert J, Hoffmann L (2000) Recent trends in rainfall-runoff characteristics in the Alzette River basin, Luxembourg. Clim Chang 45:323–337

    Article  Google Scholar 

  • Pfister L, Barnich F, Bouchet A, El Idrissi A, Hoffmann L, Iffly JF, Matgen P, Salvia-Castellví M, Taillez C, Van-den-Bos R, Hofmann H, Kies A, Stellato L, Tosheva Z (2006) Cycleau project final report. National Research Fund—Program ‘Eau’. Centre de Recherche Public—Gabriel Lippmann, Département Environnement et Biotechnologies and Uniersité du Luxembourg, Laboratoire de Physique des Radiation.

  • Phillips JM, Russell MA, Walling DE (2000) Time-integrated sampling of fluvial suspended sediment: a simple methodology for small catchments. Hydr Process 14:2589–2602

    Article  Google Scholar 

  • Poulenard J, Perrette Y, Fanget B, Quetin P, Trevisan D, Dorioz JM (2009) Infrared spectroscopy tracing of sediment sources in a small rural watershed (French Alps). Sci Tot Environ 407:2808–2819

    Article  CAS  Google Scholar 

  • Reeves J III, McCarty G (2001) Quantitative analysis of agricultural soils using near infrared reflectance spectroscopy and a fibre-optic probe. J Near Infrared Spectrosc 9:25–34

    Article  CAS  Google Scholar 

  • Reeves J III, McCarty G, Meisinger J (1999) Near infrared reflectance spectroscopy for the analysis of agricultural soils. J Near Infrared Spectrosc 7:179–193

    Article  CAS  Google Scholar 

  • Rowan JS, Goodwill P, Franks SW (2000) Uncertainty estimation in fingerprinting suspended sediment sources. In: Foster IDL (ed) Tracers in geomorphology. Wiley, Chichester, pp 279–290

    Google Scholar 

  • Russell MA, Walling DE, Hodgkinson RA (2001) Suspended sediment sources in two small lowland agricultural catchments in the UK. J Hydr 252:1–24

    Article  CAS  Google Scholar 

  • Salvia-Castellví M, Iffly JF, Vander Borght P, Hoffmann L (2005) Dissolved and particulate nutrient export from rural catchments: a case study from Luxembourg. Sci Tot Environ 344:51–65

    Article  CAS  Google Scholar 

  • Savitzky A, Golay MJ (1964) Smoothing and differentiation of data by simplified least square procedures. Anal Chem 36:1627–1639

    Article  CAS  Google Scholar 

  • Shepherd K, Walsh M (2002) Development of reflectance spectral libraries for characterization of soil properties. Soil Soc Am J 66:988–998

    CAS  Google Scholar 

  • Shibusawa S, Imade Anom S, Sato S, Sasao A, Hirako S (2001) Soil mapping using the real-time soil spectrophotometer. In: Grenier G, Blackmore S (eds) EFPA 2001, Third European Conference on Precision Agriculture, vol. 1. Agro Montpellier, pp. 497–508

  • Shonk GA, Gaultney LD, Schulze DG, Van Scoyoc GE (1991) Spectroscopic sensing of soil organic matter content. Tran Am Soc Agric Eng 34:1978–1984

    Google Scholar 

  • Small IF, Rowan JS, Franks SW, Wyatt A, Duck RW (2004) Sediment fingerprinting using a Bayesian approach yields a robust tool for environmental forensic applications. In: Croft DA, Pye K (eds) Forensic geosciences: principles, techniques and applications, vol 232. Geological Society Special Publication, London, pp 207–213

    Google Scholar 

  • Stevens A, Wesemael B, Bartholomeus H, Rosillon D, Tychon B, Ben-Dor E (2008) Laboratory, field and airborne spectroscopy for monitoring organic carbon in agricultural soils. Geoderma 144:395–404

    Article  CAS  Google Scholar 

  • Terhoeve-Urselmans T, Schmidt H, Joergensen RG, Ludwig B (2008) Usefulness of near-infrared spectroscopy to determine biological and chemical soil properties: importance of sample pre-treatment. Soil Biol Biochem 40:1178–1188

    Article  CAS  Google Scholar 

  • Udelhoven T, Emmerling C, Jarmer T (2003) Quantitative analysis of soil chemical properties with diffuse reflectance spectrometry and partial least-square regression: a feasibility study. Plant Soil 251:319–329

    Article  CAS  Google Scholar 

  • Van den Bos R, Hoffmann L, Juilleret J, Matgen P, Pfister L (2006) Conceptual modelling of individual HRU’s as a trade-off between bottom-up and top-down modelling, a case study. Conf. Environmental Modelling and Software. Proc. 3rd Bien Meet Int Enviro Model Softw Soc. Vermont, USA

  • Viscarra Rossel RA (2008) ParLeS: software for chemometric analysis of spectroscopic data. Chemom Intell Lab Syst 90:72–83

    Article  CAS  Google Scholar 

  • Viscarra Rossel R, McBratney A (1998) Laboratory evaluation of a proximal sensing technique for simultaneous measurement of clay and water content. Geoderma 85:19–39

    Article  Google Scholar 

  • Viscarra Rossel R, Walvoort D, McBratney A, Janik L, Skjemstad J (2006) Visible, near infrared, mid infrared or combined diffuse reflectance spectroscopy for simultaneous assessment of various soil properties. Geoderma 131:59–75

    Article  CAS  Google Scholar 

  • Walden J, Slattery MC, Burt TP (1997) Use of mineral magnetic measurements to fingerprint suspended sediment sources: approaches and techniques for data analysis. J Hydr 202:353–372

    Article  Google Scholar 

  • Walling DE (2005) Tracing suspended sediment sources in catchments and river systems. Sci Total Environ 344:159–184

    Article  CAS  Google Scholar 

  • Walling DE, Woodward JC (1992) Use of radiometric fingerprints to derive information on suspended sediment sources. In: Erosion and Sediment Transport Monitoring Programmes in River Basins. IAHS 210:153–164

    Google Scholar 

  • Walling DE, Owens PN, Leeks GJL (1999) Fingerprinting suspended sediment sources in the catchment of the River Ouse, Yorkshire, UK. Hydr Process 13:955–975

    Article  Google Scholar 

  • Wu Y, Chen J, Ji J, Gong P, Liao Q, Tian Q, Ma H (2007) A mechanism study of reflectance spectroscopy for investigating heavy metals in soil. Soil Soc Am J 71:918–926

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This study was supported by the ‘Ministère de l’Enseignement Supérieur et de la Recherche du Grand-Duché de Luxembourg’. Some results were achieved with support from the INTERREG IVB North-West Europe project FORESTCLIM. The authors would like to thank A. Kies and Z. Tosheva from the Radiation Physics Laboratory at the University of Luxembourg for radionuclide analysis, the ‘Administration des Services Techniques de l’Agriculture’ in Ettelbruck (Luxembourg) for total C and N analysis, the Remote Sensing Department at the University of Trier (Germany) for the access to the spectral reflectance equipment, as well as J. Ziebel, C. Guignard and F. Barnich at the CRP-Gabriel Lippmann for their help with ICP-MS and P measurements. Thanks are also extended to C. Hissler, at the same research institute, and P.N. Owens, at the University of Northern British Columbia, for providing insightful comments on the research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Núria Martínez-Carreras.

Additional information

Responsible editor: Bernhard Westrich

Rights and permissions

Reprints and permissions

About this article

Cite this article

Martínez-Carreras, N., Krein, A., Udelhoven, T. et al. A rapid spectral-reflectance-based fingerprinting approach for documenting suspended sediment sources during storm runoff events. J Soils Sediments 10, 400–413 (2010). https://doi.org/10.1007/s11368-009-0162-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11368-009-0162-1

Keywords