乐胖代购免代理版

{"id":"https://openalex.org/W4200472778","doi":"https://doi.org/10.1002/jcc.26803","title":"Mechanistic study of cobalt(I)\u2010catalyzed asymmetric coupling of ethylene and enynes to functionalized cyclobutanes","display_name":"Mechanistic study of cobalt(I)\u2010catalyzed asymmetric coupling of ethylene and enynes to functionalized cyclobutanes","publication_year":2021,"publication_date":"2021-12-24","ids":{"openalex":"https://openalex.org/W4200472778","doi":"https://doi.org/10.1002/jcc.26803","pmid":"https://pubmed.ncbi.nlm.nih.gov/34951487"},"language":"en","primary_location":{"is_oa":false,"landing_page_url":"https://doi.org/10.1002/jcc.26803","pdf_url":null,"source":{"id":"https://openalex.org/S21117631","display_name":"Journal of Computational Chemistry","issn_l":"0192-8651","issn":["0192-8651","1096-987X"],"is_oa":false,"is_in_doaj":false,"is_indexed_in_scopus":true,"is_core":true,"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false},"type":"article","type_crossref":"journal-article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5030542465","display_name":"Runfeng Huang","orcid":null},"institutions":[{"id":"https://openalex.org/I134687103","display_name":"Nanjing Tech University","ror":"https://ror.org/03sd35x91","country_code":"CN","type":"education","lineage":["https://openalex.org/I134687103"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Runfeng Huang","raw_affiliation_strings":["School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China"],"affiliations":[{"raw_affiliation_string":"School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China","institution_ids":["https://openalex.org/I134687103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075973287","display_name":"Jiali Cai","orcid":"https://orcid.org/0000-0001-8593-8345"},"institutions":[{"id":"https://openalex.org/I134687103","display_name":"Nanjing Tech University","ror":"https://ror.org/03sd35x91","country_code":"CN","type":"education","lineage":["https://openalex.org/I134687103"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jiali Cai","raw_affiliation_strings":["School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China"],"affiliations":[{"raw_affiliation_string":"School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China","institution_ids":["https://openalex.org/I134687103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5045164504","display_name":"Lei Yao","orcid":"https://orcid.org/0000-0002-2680-1629"},"institutions":[{"id":"https://openalex.org/I134687103","display_name":"Nanjing Tech University","ror":"https://ror.org/03sd35x91","country_code":"CN","type":"education","lineage":["https://openalex.org/I134687103"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Lei Yao","raw_affiliation_strings":["School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China"],"affiliations":[{"raw_affiliation_string":"School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China","institution_ids":["https://openalex.org/I134687103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5026188225","display_name":"Yuna Bai","orcid":null},"institutions":[{"id":"https://openalex.org/I134687103","display_name":"Nanjing Tech University","ror":"https://ror.org/03sd35x91","country_code":"CN","type":"education","lineage":["https://openalex.org/I134687103"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuna Bai","raw_affiliation_strings":["School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China"],"affiliations":[{"raw_affiliation_string":"School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China","institution_ids":["https://openalex.org/I134687103"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100612547","display_name":"Kai Guo","orcid":"https://orcid.org/0000-0002-0013-3263"},"institutions":[{"id":"https://openalex.org/I134687103","display_name":"Nanjing Tech University","ror":"https://ror.org/03sd35x91","country_code":"CN","type":"education","lineage":["https://openalex.org/I134687103"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Kai Guo","raw_affiliation_strings":["College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, China"],"affiliations":[{"raw_affiliation_string":"College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing, China","institution_ids":["https://openalex.org/I134687103"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5063708327","display_name":"Lili Zhao","orcid":"https://orcid.org/0000-0003-2580-6919"},"institutions":[{"id":"https://openalex.org/I134687103","display_name":"Nanjing Tech University","ror":"https://ror.org/03sd35x91","country_code":"CN","type":"education","lineage":["https://openalex.org/I134687103"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Lili Zhao","raw_affiliation_strings":["School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China"],"affiliations":[{"raw_affiliation_string":"School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Nanjing Tech University, Nanjing, China","institution_ids":["https://openalex.org/I134687103"]}]}],"institution_assertions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5063708327"],"corresponding_institution_ids":["https://openalex.org/I134687103"],"apc_list":{"value":4840,"currency":"USD","value_usd":4840,"provenance":"doaj"},"apc_paid":null,"fwci":0.096,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.234707,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":57,"max":67},"biblio":{"volume":"43","issue":"7","first_page":"440","last_page":"447"},"is_retracted":false,"is_paratext":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.9996,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.9996,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.999,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.9986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cyclobutene","display_name":"Cyclobutene","score":0.79004824},{"id":"https://openalex.org/keywords/cyclobutanes","display_name":"Cyclobutanes","score":0.7187532},{"id":"https://openalex.org/keywords/reductive-elimination","display_name":"Reductive elimination","score":0.7183168},{"id":"https://openalex.org/keywords/oxidative-addition","display_name":"Oxidative addition","score":0.53936994},{"id":"https://openalex.org/keywords/enyne","display_name":"Enyne","score":0.44253838},{"id":"https://openalex.org/keywords/cyclopropene","display_name":"Cyclopropene","score":0.4415479},{"id":"https://openalex.org/keywords/catalytic-cycle","display_name":"Catalytic cycle","score":0.4310401}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.80626166},{"id":"https://openalex.org/C2776011334","wikidata":"https://www.wikidata.org/wiki/Q411757","display_name":"Cyclobutene","level":3,"score":0.79004824},{"id":"https://openalex.org/C2911029807","wikidata":"https://www.wikidata.org/wiki/Q80232","display_name":"Cyclobutanes","level":4,"score":0.7187532},{"id":"https://openalex.org/C2778815869","wikidata":"https://www.wikidata.org/wiki/Q25325213","display_name":"Reductive elimination","level":3,"score":0.7183168},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6871964},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.61867535},{"id":"https://openalex.org/C59759590","wikidata":"https://www.wikidata.org/wiki/Q2275927","display_name":"Regioselectivity","level":3,"score":0.5905821},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.5801251},{"id":"https://openalex.org/C2778597550","wikidata":"https://www.wikidata.org/wiki/Q151313","display_name":"Ethylene","level":3,"score":0.56649566},{"id":"https://openalex.org/C94882840","wikidata":"https://www.wikidata.org/wiki/Q2123471","display_name":"Oxidative addition","level":3,"score":0.53936994},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.47010535},{"id":"https://openalex.org/C515602321","wikidata":"https://www.wikidata.org/wiki/Q740","display_name":"Cobalt","level":2,"score":0.4446187},{"id":"https://openalex.org/C2780588603","wikidata":"https://www.wikidata.org/wiki/Q3589015","display_name":"Enyne","level":3,"score":0.44253838},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.44191244},{"id":"https://openalex.org/C2777320604","wikidata":"https://www.wikidata.org/wiki/Q414101","display_name":"Cyclopropene","level":2,"score":0.4415479},{"id":"https://openalex.org/C65024703","wikidata":"https://www.wikidata.org/wiki/Q373406","display_name":"Reaction mechanism","level":3,"score":0.4405647},{"id":"https://openalex.org/C63338738","wikidata":"https://www.wikidata.org/wiki/Q287862","display_name":"Catalytic cycle","level":3,"score":0.4310401},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.41257802},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.40420815},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2040089}],"mesh":[],"locations_count":2,"locations":[{"is_oa":false,"landing_page_url":"https://doi.org/10.1002/jcc.26803","pdf_url":null,"source":{"id":"https://openalex.org/S21117631","display_name":"Journal of Computational Chemistry","issn_l":"0192-8651","issn":["0192-8651","1096-987X"],"is_oa":false,"is_in_doaj":false,"is_indexed_in_scopus":true,"is_core":true,"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false},{"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/34951487","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_indexed_in_scopus":false,"is_core":false,"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":["National Institutes of Health"],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/6","display_name":"Clean water and sanitation","score":0.67}],"grants":[{"funder":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China","award_id":"21973044"},{"funder":"https://openalex.org/F4320322769","funder_display_name":"Natural Science Foundation of Jiangsu Province","award_id":"BK20211587"},{"funder":"https://openalex.org/F4320324983","funder_display_name":"Nanjing Tech University","award_id":"39837132"},{"funder":"https://openalex.org/F4320324983","funder_display_name":"Nanjing Tech University","award_id":"39837123"}],"datasets":[],"versions":[],"referenced_works_count":52,"referenced_works":["https://openalex.org/W1418486776","https://openalex.org/W1978581772","https://openalex.org/W1988091937","https://openalex.org/W1992173555","https://openalex.org/W2011215428","https://openalex.org/W2013276134","https://openalex.org/W2029667189","https://openalex.org/W2030687437","https://openalex.org/W2041984396","https://openalex.org/W2045571822","https://openalex.org/W2045596332","https://openalex.org/W2046158356","https://openalex.org/W2050268391","https://openalex.org/W2081320501","https://openalex.org/W2086957099","https://openalex.org/W2092157292","https://openalex.org/W2096747776","https://openalex.org/W2104919283","https://openalex.org/W2110413027","https://openalex.org/W2112850441","https://openalex.org/W2119547517","https://openalex.org/W2132525235","https://openalex.org/W2132706231","https://openalex.org/W2134220433","https://openalex.org/W2150697053","https://openalex.org/W2179759039","https://openalex.org/W2322685659","https://openalex.org/W2323169631","https://openalex.org/W2327641409","https://openalex.org/W2330586915","https://openalex.org/W2331283941","https://openalex.org/W2518378475","https://openalex.org/W2543404811","https://openalex.org/W2565850597","https://openalex.org/W2735838959","https://openalex.org/W2795441230","https://openalex.org/W2809777133","https://openalex.org/W2901949184","https://openalex.org/W2921446126","https://openalex.org/W2947345772","https://openalex.org/W2950545306","https://openalex.org/W2979793950","https://openalex.org/W3021239069","https://openalex.org/W3027641328","https://openalex.org/W3034114217","https://openalex.org/W3088843017","https://openalex.org/W3122856686","https://openalex.org/W3126069146","https://openalex.org/W3127656909","https://openalex.org/W3128053647","https://openalex.org/W3153652283","https://openalex.org/W3185122837"],"related_works":["https://openalex.org/W4285158882","https://openalex.org/W4233507084","https://openalex.org/W3201793335","https://openalex.org/W2950373311","https://openalex.org/W2892788422","https://openalex.org/W2143191309","https://openalex.org/W2134220433","https://openalex.org/W2110566078","https://openalex.org/W2091082492","https://openalex.org/W2034168282"],"abstract_inverted_index":{"Density":[0],"functional":[1],"theory":[2],"(DFT)":[3],"calculations":[4],"have":[5],"been":[6],"performed":[7],"to":[8,30,99],"gain":[9],"insight":[10],"into":[11],"the":[12,16,32,43,53,70,74,80,102,108,113,131,134,151,156,161,168],"reaction":[13,23],"mechanism":[14],"of":[15,24,82,133,141,163,167],"Co(I)-catalyzed":[17],"asymmetric":[18],"[2":[19],"+":[20],"2]":[21],"cycloaddition":[22],"enyne":[25],"1a":[26],"with":[27,79,138],"ethylene":[28,85],"2":[29],"give":[31],"functionalized":[33],"cyclobutene":[34],"E-4a":[35,105],"possessing":[36],"a":[37,139],"chiral,":[38],"all-carbon":[39],"quaternary":[40],"center":[41],"in":[42,101],"ring":[44],"framework":[45],"(Science,":[46],"361,":[47],"68-72).":[48],"This":[49],"study":[50],"reveals":[51],"that":[52],"whole":[54,157],"catalysis":[55],"can":[56],"be":[57,150],"characterized":[58],"via":[59,86],"three":[60],"stages:":[61],"(i)":[62],"oxidative":[63,88],"dimerization":[64,89],"followed":[65],"by":[66],"reductive":[67,95],"elimination":[68,93,96],"gives":[69],"intermediate":[71],"IM3,":[72],"(ii)":[73],"alkenyl-Co(III)":[75,135],"metallacycloheptene":[76,136],"IM6":[77,98],"formation":[78,132],"addition":[81],"another":[83],"equivalent":[84],"an":[87],"process,":[90],"(iii)":[91],"\u03b2-Hydrogen":[92],"and":[94,106,121,130,165],"from":[97],"result":[100],"final":[103],"product":[104,169],"regenerate":[107],"active":[109],"speices":[110],"IM1":[111],"for":[112,124],"next":[114],"catalytic":[115],"cycle.":[116],"Each":[117],"stage":[118],"is":[119],"kinetically":[120],"thermodynamically":[122],"feasible":[123],"experimental":[125],"realization":[126],"under":[127],"mild":[128],"conditions,":[129],"IM6,":[137],"barrier":[140],"27.2":[142],"kcal":[143],"mol-1":[144],"(i.e.,":[145],"IM2":[146],"\u2192":[147],"TS4),":[148],"should":[149],"rate-determining":[152],"step":[153],"(RDS)":[154],"during":[155],"catalysis.":[158],"In":[159],"addition,":[160],"origins":[162],"enantioselectivity":[164],"regioselectivity":[166],"are":[170],"discussed.":[171]},"cited_by_api_url":"https://api.openalex.org/works?filter=cites:W4200472778","counts_by_year":[{"year":2024,"cited_by_count":1}],"updated_date":"2025-01-18T10:26:18.862688","created_date":"2021-12-31"}