{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,9,20]],"date-time":"2024-09-20T16:30:40Z","timestamp":1726849840522},"reference-count":30,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2019,3,18]],"date-time":"2019-03-18T00:00:00Z","timestamp":1552867200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["17-73-10284","18-19-00151"],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Government of Russian Federation","award":["08-08"]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Sensors"],"abstract":"Currently, there are no established procedures for limit of detection (LOD) evaluation in multisensor system studies, which complicates their correct comparison with other analytical techniques and hinders further development of the method. In this study we propose a simple and visually comprehensible approach for LOD estimation in multisensor analysis. The suggested approach is based on the assessment of evolution of mean relative error values in calibration series with growing analyte concentration. The LOD value is estimated as the concentration starting from which MRE values become stable from sample to sample. This intuitive procedure was successfully tested with a variety of real data from potentiometric multisensor systems.<\/jats:p>","DOI":"10.3390\/s19061359","type":"journal-article","created":{"date-parts":[[2019,3,19]],"date-time":"2019-03-19T16:12:25Z","timestamp":1553011945000},"page":"1359","source":"Crossref","is-referenced-by-count":33,"title":["A Simple Procedure to Assess Limit of Detection for Multisensor Systems"],"prefix":"10.3390","volume":"19","author":[{"given":"Ekaterina","family":"Oleneva","sequence":"first","affiliation":[{"name":"Institute of Chemistry, Saint-Petersburg State University, Universitetskaya emb., 7-9-11, 199304 Saint-Petersburg, Russia"},{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-0202-6338","authenticated-orcid":false,"given":"Maria","family":"Khaydukova","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint-Petersburg State University, Universitetskaya emb., 7-9-11, 199304 Saint-Petersburg, Russia"},{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]},{"given":"Julia","family":"Ashina","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint-Petersburg State University, Universitetskaya emb., 7-9-11, 199304 Saint-Petersburg, Russia"},{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-5775-6878","authenticated-orcid":false,"given":"Irina","family":"Yaroshenko","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint-Petersburg State University, Universitetskaya emb., 7-9-11, 199304 Saint-Petersburg, Russia"},{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]},{"given":"Igor","family":"Jahatspanian","sequence":"additional","affiliation":[{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-8656-0145","authenticated-orcid":false,"given":"Andrey","family":"Legin","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint-Petersburg State University, Universitetskaya emb., 7-9-11, 199304 Saint-Petersburg, Russia"},{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-5667-6910","authenticated-orcid":false,"given":"Dmitry","family":"Kirsanov","sequence":"additional","affiliation":[{"name":"Institute of Chemistry, Saint-Petersburg State University, Universitetskaya emb., 7-9-11, 199304 Saint-Petersburg, Russia"},{"name":"Laboratory of Artificial Sensory Systems, ITMO University, Kronverksky pr., 49, 197101 Saint-Petersburg, Russia"}]}],"member":"1968","published-online":{"date-parts":[[2019,3,18]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1965","DOI":"10.1351\/pac200577111965","article-title":"Nonspecific sensor arrays (\u201celectronic tongue\u201d) for chemical analysis of liquids (IUPAC Technical Report)","volume":"77","author":"Vlasov","year":"2005","journal-title":"Pure Appl. Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"2481","DOI":"10.1039\/c0an00292e","article-title":"Recent advances in electronic tongues","volume":"135","author":"Riul","year":"2010","journal-title":"Analyst"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"1539","DOI":"10.1002\/elan.201000013","article-title":"Electronic tongues employing electrochemical sensors","volume":"22","year":"2010","journal-title":"Electroanalysis"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"282","DOI":"10.1016\/j.snb.2012.09.106","article-title":"Water toxicity evaluation in terms of bioassay with an Electronic Tongue","volume":"179","author":"Kirsanov","year":"2013","journal-title":"Sens. Actuators B"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"1429","DOI":"10.1021\/cr300076c","article-title":"Instrumental methods (spectroscopy, electronic nose, and tongue) as tools to predict taste and aroma in beverages: Advantages and limitations","volume":"113","author":"Smyth","year":"2013","journal-title":"Chem. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1021\/acssensors.7b00709","article-title":"A hand-held optoelectronic nose for the identification of liquors","volume":"3","author":"Li","year":"2018","journal-title":"ACS Sens."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1080\/01971360.2018.1495480","article-title":"Colorimetric sensor arrays: Development and application to art conservation","volume":"57","author":"LaGasse","year":"2018","journal-title":"J. Am. Inst. Conserv."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.aca.2015.01.017","article-title":"Practical guidelines for reporting results in single- and multi-component analytical calibration: A tutorial","volume":"868","author":"Olivieri","year":"2015","journal-title":"Anal. Chem. Acta"},{"key":"ref_9","unstructured":"Vlasov, Y. (2011). Problems of Analytical Chemistry, Nauka."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"2527","DOI":"10.1351\/pac199466122527","article-title":"Recommendations for nomenclature of ionselective electrodes","volume":"66","author":"Buck","year":"1994","journal-title":"Pure Appl. Chem."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1016\/j.trac.2005.01.003","article-title":"Potentiometric sensors for trace-level analysis","volume":"24","author":"Bakker","year":"2005","journal-title":"Trends Anal. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"181","DOI":"10.1002\/(SICI)1099-128X(199705)11:3<181::AID-CEM459>3.0.CO;2-7","article-title":"Propagation of measurement errors for the validation of predictions obtained by principal component regression and partial least squares","volume":"11","author":"Faber","year":"1997","journal-title":"J. Chemometr."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/S0169-7439(03)00110-2","article-title":"Capability of detection of an analytical method evaluating false positive and false negative (ISO 11843) with partial least squares","volume":"69","author":"Ortiz","year":"2003","journal-title":"Chemom. Intell. Lab. Syst."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/0169-7439(88)80065-0","article-title":"Multivariate detection limits for selected ion monitoring gas chromatography-mass spectrometry","volume":"3","author":"Delaney","year":"1988","journal-title":"Chemom. Intell. Lab. Syst."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1016\/S0169-7439(98)00195-6","article-title":"Multivariate detection limits with fixed probabilities of error","volume":"45","author":"Larrechi","year":"1999","journal-title":"Chemom. Intell. Lab. Syst."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"133","DOI":"10.1016\/S0169-7439(01)00204-0","article-title":"Standard error of prediction for multiway PLS: 1. Background and a simulation study","volume":"61","author":"Faber","year":"2002","journal-title":"Chemom. Intell. Lab. Syst."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1620","DOI":"10.1021\/ac960862b","article-title":"Net Analyte Signal Calculation in Multivariate Calibration","volume":"69","author":"Lorber","year":"1997","journal-title":"Anal. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"436","DOI":"10.1016\/j.proeng.2016.11.538","article-title":"Using Net Analyte Signal to Estimate the Limit of Detection in Temperature-modulated MOX Sensors","volume":"168","author":"Marco","year":"2016","journal-title":"Procedia Eng."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"7858","DOI":"10.1021\/ac501786u","article-title":"IUPAC-Consistent Approach to the Limit of Detection in Partial Least-Squares Calibration","volume":"86","author":"Allegrini","year":"2014","journal-title":"Anal. Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"5358","DOI":"10.1021\/cr400455s","article-title":"Analytical Figures of Merit: From Univariate to Multiway Calibration","volume":"114","author":"Olivieri","year":"2014","journal-title":"Chem. Rev."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1002\/cem.716","article-title":"A simple approach to uncertainty propagation in preprocessed multivariate calibration","volume":"16","author":"Olivieri","year":"2002","journal-title":"J. Chemom."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.aca.2015.11.028","article-title":"Generalized error-dependent prediction uncertainty in multivariate calibration","volume":"903","author":"Allegrini","year":"2016","journal-title":"Anal. Chim. Acta"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"633","DOI":"10.1351\/pac200678030633","article-title":"Uncertainty estimation and figures of merit for multivariate calibration (IUPAC Technical Report)","volume":"78","author":"Olivieri","year":"2006","journal-title":"Pure Appl. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/j.aca.2018.03.005","article-title":"Multivariate estimation of the limit of detection by orthogonal partial least squares in temperature-modulated MOX sensors","volume":"1019","author":"Santiago","year":"2018","journal-title":"Anal. Chim. Acta"},{"key":"ref_25","first-page":"47","article-title":"The distribution of the largest of a set of estimated variances as a fraction of their total","volume":"11","author":"Cochran","year":"1941","journal-title":"Ann. Hum. Genet."},{"key":"ref_26","unstructured":"(1994). ISO Standard 5725\u20132:1994: Accuracy (Trueness and Precision) of Measurement Methods and Results\u2014Part 2: Basic Method for the Determination of Repeatability and Reproducibility of a Standard Measurement Method, International Organization for Standardization."},{"key":"ref_27","first-page":"68","article-title":"Scrutiny of variance results for outliers: Cochran\u2019s test optimized","volume":"659","year":"2012","journal-title":"Anal. Chim. Acta"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1002\/elan.201100439","article-title":"Potentiometric Sensor Array for Analysis of Complex Rare Earth Mixtures","volume":"24","author":"Kirsanov","year":"2012","journal-title":"Electroanalysis"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"556","DOI":"10.1016\/j.talanta.2014.08.030","article-title":"Determination of urine ionic composition with potentiometric multisensor system","volume":"131","author":"Yaroshenko","year":"2015","journal-title":"Talanta"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"109","DOI":"10.1016\/S0169-7439(01)00155-1","article-title":"PLS-regression: A basic tool of chemometrics","volume":"58","author":"Wold","year":"2001","journal-title":"Chemom. Intell. Lab. 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