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The resulting leapfrog B24<\/jats:sub>has either a bowl shape with a square vacancy or a quasi\u2010planar 2D close\u2010packed triangular boron sheet. The neutral and ionic forms of the latter are found to be more stable than their homologous leapfrog bowl clusters, with the exception of the dicationic B24<\/jats:sub>+2<\/jats:sup>. While the leapfrog isomer is less stable than the tubular double ring in the neutral state, it becomes competitive in some ionic states. The nucleus independent chemical shift, electron localization function, ring current maps and the electronic structure of leapfrog B24<\/jats:sub>clusters reveal them to behave as aromatics.<\/jats:p>","DOI":"10.1002\/jcc.26434","type":"journal-article","created":{"date-parts":[[2020,10,16]],"date-time":"2020-10-16T13:04:01Z","timestamp":1602853441000},"page":"72-80","update-policy":"http:\/\/dx.doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Structure, stability and bonding of the leapfrogB24<\/sub>0<\/sup><\/scp>,\u00b11,\u00b12<\/sup>"],"prefix":"10.1002","volume":"42","author":[{"ORCID":"http:\/\/orcid.org\/0000-0003-4527-2619","authenticated-orcid":false,"given":"Jules Tshishimbi","family":"Muya","sequence":"first","affiliation":[{"name":"Department of Chemistry, Faculty of Sciences University of Kinshasa Kinshasa Democratic Republic of the Congo"},{"name":"Research Center for Theoretical Chemistry and Physics in Central Africa Faculty of Science, University of Kinshasa Kinshasa Democratic Republic of the Congo"},{"name":"Department of Chemistry Hanyang University Seoul South Korea"}]},{"ORCID":"http:\/\/orcid.org\/0000-0003-3278-3284","authenticated-orcid":false,"given":"Bienfait Kabuyaya","family":"Isamura","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Sciences University of Kinshasa Kinshasa Democratic Republic of the Congo"},{"name":"Research Center for Theoretical Chemistry and Physics in Central Africa Faculty of Science, University of Kinshasa Kinshasa Democratic Republic of the Congo"}]},{"ORCID":"http:\/\/orcid.org\/0000-0001-6761-9295","authenticated-orcid":false,"given":"Issofa","family":"Patouossa","sequence":"additional","affiliation":[{"name":"Research Center for Theoretical Chemistry and Physics in Central Africa Faculty of Science, University of Kinshasa Kinshasa Democratic Republic of the Congo"},{"name":"Faculty of Sciences, Laboratory of Physical and Theoretical Chemistry University of Yaound\u00e9 I Yaound\u00e9 Cameroon"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-3803-0569","authenticated-orcid":false,"given":"Minh Tho","family":"Nguyen","sequence":"additional","affiliation":[{"name":"Department of Chemistry, KU Leuven Leuven Belgium"},{"name":"Institute for Computational Science and Technology (ICST) Ho Chi Minh City Vietnam"}]},{"ORCID":"http:\/\/orcid.org\/0000-0002-1288-1664","authenticated-orcid":false,"given":"Arnout","family":"Ceulemans","sequence":"additional","affiliation":[{"name":"Department of Chemistry, KU Leuven Leuven Belgium"}]}],"member":"311","published-online":{"date-parts":[[2020,10,16]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(94)01449-6"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.473841"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.454989"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-461X(2000)78:2<131::AID-QUA6>3.0.CO;2-3"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/qua.21171"},{"key":"e_1_2_7_7_1","doi-asserted-by":"crossref","first-page":"01251","DOI":"10.1103\/PhysRevA.98.012501","volume":"98","author":"Ferrari P.","year":"2018","journal-title":"Phys. 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