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Synapses modulated by light signals, which are also referred as photonic synapses, can not only make effective use of the outstanding properties of light to provide devices with ultrahigh propagation speed, high bandwidth and low crosstalk but also provide a noncontact writing method, which can facilitate the evolution of optical wireless communication and operation. More importantly, real\u2010time image processing can also be performed by photonic synapses which possess temporary memory. Thus far, tremendous efforts have been taken to design and fabricate photonic synapses. Herein, a summary of the development of different kinds of emerging materials utilized in photonic synaptic devices including memristors, field\u2010effect transistors, and phase change memory is presented, followed by the innovative applications of photonic synapses for neuromorphic systems. 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